| 1 | 5 | Tim Rech / Mark Wamala | vs | Stefan von Gartzen / Jannis Florian | 1:1 |
| 2 | 6 | Jinjing Ge / Axel Paulsen | vs | Tobias Janning / Loredana Pinna | 0:2 |
| 3 | 8 | Bela Günther / Tim Wedemann | vs | Artur Lerm / Kim Zülsdorff | 0:2 |
| 4 | 12 | Julia Trabert / Benjamin Krauß | vs | Lydia Visser / Theresa Theurer | 2:0 |
| 5 | 13 | Mario Christ / Max Mulsow | vs | Bernd Schiffers / Barbara Gerlach | 1:1 |
| 6 | 14 | Frank Böhm / Zina Rupp | vs | Maximilian Klötzer / David Hansen | 1:1 |
| 7 | 15 | Montassar Alibi / Djamila Nader | vs | Kathrin Anja Victoria Krones / Linus Koch | 1:1 |
| 8 | 16 | Mike Kaufmann / Ben Fritsch | vs | Jessica Köhnke / Marco Last | 2:0 |
| 9 | 17 | Julia Böhnlein / Adrian Sutaj | vs | Christian Simon / Daniel Pöche | 1:1 |
| 10 | 18 | Lars Porrmann / Lars Hitz | vs | Allan Ullrich / Nicole Retzlaff | 1:1 |
| 11 | 10 | Chris Eggers / Valentina Schmitz | vs | Rabie Samakeh / Peter Dahlke | 2:0 |
| 12 | 16 | Finn Meyer / Kilian Hodrus | vs | Sabrina Sachau / Steven Rauser | 0:2 |
