| 1 | 10 | Daniel Löffelholz / Knuth Strecker | vs | Dana Dodier / Jinjing Ge | 1:0 |
| 2 | 2 | Theodor Czehmann / Felix Ruckdeschel | vs | Jan Becker / Max Kammholz | 1:1 |
| 3 | 3 | Valentina Schmitz / Andrei Wilkens | vs | Ulf Van Agterveld / Julian Schulz | 0:1 |
| 4 | 4 | Arne Borck / Bela Günther | vs | Christoph Rosemann / Philip Diessner | 1:0 |
| 5 | 5 | Matthias Wilke / Caroline Vogler | vs | Janin Block / Guido Böhm | 0:1 |
| 6 | 6 | Anna Simon / Jörg Simon | vs | Mandy Reimann / Serg Paul | 0:1 |
| 7 | 7 | Jürgen Graf / Ilja Brosowski | vs | Hermann Jonas / Kirill Ermisch | 1:0 |
| 8 | 8 | Lars Schumann / Steven Rauser | vs | David Hansen / Oliver Westphal | 0:1 |
| 9 | 9 | Lars Porrmann / Sven Decken | vs | Tobias Janning / Peter Dahlke | 1:1 |
| 10 | 10 | Dennis Bless / Femi Oyeleye | vs | Luca Derksen / Aaron Barnitzke | 1:0 |
| 11 | 11 | Barbara Gerlach / Konstantin Tobisch-Haupt | vs | Thorben Harms / Mattes Bürk | 1:1 |
| 12 | 12 | Sven Reepschläger / Stefan Jung | vs | Sanna Dibowski / Theresa Theurer | 1:0 |
| 13 | 13 | Anne Schadt / Dennis Belle | vs | Finn Meyer / Marius Meyer-Hemme | 1:0 |
| 14 | 14 | Klaas Lohmann / Hakim Ikhlef | vs | Daniel Jungblut / Oliver Weihrauch | 1:0 |
| 15 | 15 | Stephan Hanschmann / Janis Zisenis | vs | André Bammesberger / Lorenz Voß | 1:0 |
| 16 | 1 | Niklas Eigler / Benjamin Trinh | vs | Minyoung Bai / Semin Mensah | 0:1 |
| 17 | 16 | Joschka Wagner / Richard Günther | vs | Steven Falkert / Erick Riadi | 1:0 |
| 18 | 6 | Mike Kaufmann / Sina Calberlah | vs | Klemens Naumann / Sabrina Sachau | 1:0 |
| 19 | 8 | Julia Böhnlein / Kathrin Anja Victoria Krones | vs | Lucas Neumann / Christian Honsel | 1:1 |
| 20 | 1 | Ivo Pinheiro / Daniel Pöche | vs | Nico Wohlgemuth / My Linh Tran | 0:1 |
| 21 | 2 | Alexander Freiherr von Seld / Niels Porsiel | vs | Benjamin Eils / Nick Kinast | 0:1 |
| 22 | 7 | Matthias Wester-Ebbinghaus / Gerd Bremer | vs | Wiebke von Osten / Maximilian Hoyer | 0:1 |
| 23 | 9 | Tjorben Gschwander / Artur Lerm | vs | Thomas Grotz / Uwe Selent | 1:0 |
| 24 | 11 | Julia Wohlgemuth / Silas Reimann | vs | Alexander Graf / Sebastian Sommer | 1:0 |
| 25 | 16 | Stefan von Gartzen / Jessica Köhnke | vs | Rabie Samakeh / Tim Wedemann | 0:1 |
| 26 | 5 | Maura Porrmann / Antonia Nuguid | vs | Viktor Vasilev / László Földesi | 1:0 |
| 27 | 13 | Julia Voecks / Loredana Pinna | vs | Björn Krutzki / Adrian Sutaj | 0:1 |
| 28 | 12 | Dennis Trepkau / Miriam Grunau | vs | Aljoscha Lein / Robih Mariam | 0:1 |
| 29 | 3 | Jonas Roeer / Frederik Buchmann | vs | Mario Christ / lydia Visser | 0:1 |
| 30 | 15 | Paul Scheffler / Peter Große | vs | Ahmad Alsayed / Jan Eschweiler-Voecks | 0:1 |
| 31 | 4 | Pia-Louise Claußen / Helena Bair | vs | Kerstin Tschischka / Stefanie Schmid | 0:1 |
| 32 | | Alexander Schwarz / Marcel Limburg | vs | Freilos | 1:0 |
