| 1 | 18 | Klaas Lohmann / Daniel Jungblut | vs | Alexander Graf / Daniel Löffelholz | 0:1 |
| 2 | 2 | Felix Simmendinger / Allan Ullrich | vs | Justin Werners / Sinan Cinkaya | 0:1 |
| 3 | 3 | Benjamin Krauß / Moritz Kramer | vs | Ivo Pinheiro / Jinjing Ge | 0:1 |
| 4 | 4 | Sina Calberlah / Tim Wedemann | vs | Jerome Technau / Sebastian Sommer | 0:1 |
| 5 | 5 | Joshua Supra / Christoph Rosemann | vs | Sebastian Mader / Michael Niestedt | 0:1 |
| 6 | 6 | Marco Last / Stefan von Gartzen | vs | Klemens Naumann / Julia Wohlgemuth | 1:0 |
| 7 | 7 | Dennis Belle / Marlen Hoyer-Weise | vs | Puyan Sattarian / Jan Schlicht | 0:1 |
| 8 | 8 | Ilja Pavkovic / Sören Schlotfeldt | vs | Rikko Tüitjer / Viktor Vasilev | 0:1 |
| 9 | 9 | Finn Meyer / Oliver Weihrauch | vs | Dennis Lützow / Jürgen Graf | 1:0 |
| 10 | 10 | Thorben Harms / Florian Lienkamp | vs | Mehmet Arslan / Frank Böckeler | 0:1 |
| 11 | 1 | Tony Spredeman / Silvia Pintilii | vs | Tom Knoth / Anne Dworatzek | 1:0 |
| 12 | 12 | Lars Porrmann / Kathrin Anja Victoria Krones | vs | Julian Kaltenbach / Amat Hildebrand | 0:1 |
| 13 | 13 | Philip Diessner / Aaron Fritzsche | vs | Antonia Nuguid / Theresa Theurer | 1:1 |
| 14 | 14 | Jan-Hendrik Wolf / Richard Günther | vs | Vera Büssing / Jonas Langer | 1:0 |
| 15 | 15 | Morris Jaensch / Bernhard Jürgens | vs | Hannah Wilkens / Sarah Walter | 1:0 |
| 16 | 16 | Rabie Samakeh / Celine Hofer | vs | Michael Roßnick / Julian Schulz | 1:0 |
| 17 | 17 | Kai Maercklin / Caroline Vogler | vs | Loredana Pinna / Sabrina Sachau | 0:1 |
| 18 | 1 | Valentina Schmitz / Mattes Bürk | vs | Sandra Ranff / Mounir Mrabtine | 1:0 |
| 19 | 11 | Guido Böhm / Janin Block | vs | Mario Christ / Nicola Gehrlein | 0:1 |
| 20 | 8 | Sanna Dibowski / Moritz Josten | vs | Adrian Sutaj / Alexander Schauer | 1:0 |
| 21 | 4 | Felix Ruckdeschel / Valentin Weichsel | vs | Kim Zülsdorff / Julia Böhnlein | 0:1 |
| 22 | 3 | Marcus Fleck / Jan Eschweiler-Voecks | vs | Quoc Nguyen / Maximilian Hoyer | 0:1 |
| 23 | 2 | Philipp Strauch / Matthias Wilke | vs | Tom Bigalke Garcia / Otto Liedtke | 1:0 |
| 24 | 10 | Tobias Janning / Peter Dahlke | vs | Daniel Lange / Joschka Wagner | 0:1 |
| 25 | 5 | Alina Porechina / Aljoscha Würtz | vs | Steven Rauser / Marten Engel | 1:1 |
| 26 | 6 | Hermann Jonas / Nikolaus Kraft | vs | David Schott / Lars Wegener | 0:1 |
| 27 | 7 | Alexander Lahn / Marius Bull | vs | Julia Künkel / Julia Voecks | 1:1 |
| 28 | 12 | Jonas Roeer / Jan-Hendrik Ehlers | vs | Gaby Simon / Jörg Simon | 0:1 |
| 29 | 13 | Ali Nassar / Kilian Hodrus | vs | Martin Hoffmeyer / Florian Hoffmeyer | 0:1 |
| 30 | 17 | Luciano Auria / Jan Baumhögger | vs | Sven Decken / Jessica Köhnke | 1:1 |
| 31 | 15 | Mike Kaufmann / Lydia Visser | vs | David Hansen / Mo Ghadiri | 1:0 |
| 32 | 11 | Christoph Klöhn / Hans Woitke | vs | Henri Schmidt / Oliver Westphal | 0:1 |
| 33 | | Marc Schleeweiß / Emil Gasanov | vs | Freilos | 1:0 |
