| 1 | 10 | Maura Porrmann / Maximilian Hoyer | vs | Markus Weber / Felix Krause | 1:0 |
| 2 | 15 | Loredana Pinna / Jessica Köhnke | vs | Benjamin Krauß / Richard Günther | 0:1 |
| 3 | 3 | Marcus Fleck / Daniel Jungblut | vs | Sven Klaholz / Tatiana Jancusova | 1:0 |
| 4 | 5 | Kai Eggerstedt / Muhammet Ertürk | vs | Stefan von Gartzen / Mattes Bürk | 1:0 |
| 5 | 1 | Björn Brose / Björn Krutzki | vs | Stefan Jung / Igor Pagacz | 1:0 |
| 6 | 13 | Stefan Engelhardt / Michael Niestedt | vs | Luca Derksen / Aaron Barnitzke | 1:0 |
| 7 | 2 | Sabine Brose / Michael Prinz | vs | Mike Kaufmann / Oliver Westphal | 1:1 |
| 8 | 11 | Bela Günther / Joschka Wagner | vs | Isabella Tran / Celine Hofer | 0:1 |
| 9 | 12 | Klaas Lohmann / Daniel Kuschow | vs | Mario Christ / Tim Wedemann | 0:1 |
| 10 | 4 | Moritz Josten / Klemens Naumann | vs | Marten Engel / Rikko Tüitjer | 1:1 |
| 11 | 17 | Kilian Hodrus / Christian Honsel | vs | Puyan Sattarian / Ivo Pinheiro | 1:1 |
| 12 | 6 | Justin Werners / Tjorben Gschwander | vs | Adrian Sutaj / Bernd Knill | 0:1 |
| 13 | 9 | Oliver Weihrauch / Jan-Hendrik Wolf | vs | Sanna Dibowski / Antonia Nuguid | 0:1 |
| 14 | 2 | Jinjing Ge / Daniel Lange | vs | Lars Schumann / Steven Rauser | 1:0 |
| 15 | 3 | Christoph Rosemann / Philip Diessner | vs | Alexander Lahn / Veronika Ruiz | 0:1 |
| 16 | 1 | Arne Borck / Jan Sorgenfrei | vs | László Földesi / Viktor Vasilev | 1:0 |
| 17 | 5 | Nadine Fleck / Mia Reimer | vs | Finn Meyer / Knuth Strecker | 0:1 |
| 18 | 7 | Erdem Yildirim / Hannah Wilkens | vs | Dennis Lützow / Jürgen Graf | 1:0 |
| 19 | 8 | Lars Porrmann / Otto Liedtke | vs | Alina Porechina / Theresa Theurer | 1:0 |
| 20 | 13 | Paul Harald Giesen / Kim Zülsdorff | vs | Matthias Wester-Ebbinghaus / Gerd Bremer | 0:1 |
| 21 | 16 | Isabell Uhlendorf / Julia Wohlgemuth | vs | Kathrin Anja Victoria Krones / Julia Böhnlein | 1:0 |
| 22 | 10 | Ali Nassar / Caroline Vogler | vs | Manuel Gallardo / David Hansen | 1:0 |
| 23 | 18 | Simon Oehrlein / Lukas Ludwig | vs | Anne Schadt / Deniz Varvar | 0:1 |
| 24 | 15 | lydia Visser / Valentina Schmitz | vs | Rem Alinsug / Abdullah Mariam | 1:1 |
| 25 | 11 | Valentin Weichsel / Silvia Morselli | vs | Freilos | 1:0 |
