| 1 | 3 | Finn Meyer / Antonia Nuguid | vs | Artur Lerm / Katharina Ziehr | 0:1 |
| 2 | 2 | Julia Voecks / Robih Mariam | vs | Mario Christ / Valentina Schmitz | 1:0 |
| 3 | 4 | Leif Christoph / Julia Steinhorst | vs | Marcus Fleck / Nadine Fleck | 1:0 |
| 4 | 5 | Judith Glawe / Dominik Beseler | vs | Sina Calberlah / Tim Wedemann | 1:0 |
| 5 | 7 | Katharina Vierk / Jan-Hendrik Wolf | vs | Mia Reimer / Joschka Wagner | 1:0 |
| 6 | 1 | Jinjing Ge / Ahmad Jassem | vs | Dennis Belle / Anne Schadt | 1:0 |
| 7 | 9 | Quoc Nguyen / Isabell Uhlendorf | vs | Sarah Walter / Stefan Engelhardt | 1:0 |
| 8 | 6 | Alina Porechina / Oliver Westphal | vs | Sören Schlotfeldt / Kristina Tretau | 1:0 |
| 9 | 8 | Oliver Schlancke / Stefanie Schmid | vs | Bernd Knill / Sanna Dibowski | 1:0 |
| 10 | 10 | Loredana Pinna / Klaas Lohmann | vs | Julian Kaltenbach / Lara Zimansky | 1:0 |
| 11 | 11 | Svenja Tüitjer / Michael Prinz | vs | Stefan von Gartzen / Jessica Köhnke | 0:1 |
| 12 | 5 | Ulrike Althoff / Jan-Henrik Reigardt | vs | lydia Visser / Hakim Ikhlef | 1:0 |
| 13 | 2 | Mattes Bürk / Kerstin Tschischka | vs | Steven Rauser / Isabelle Heise | 0:1 |
| 14 | 3 | Kim Zülsdorff / Larissa Gebken | vs | Anna Rüpcke / Ali Nassar | 0:1 |
| 15 | | Lena Pinkerneil / Stefan Draack | vs | Freilos | 1:0 |
