| 1 | 9 | Mirza Smajic / Max Drobick | vs | Oskar Hübner / Hans-Georg Prengel | 0:1 |
| 2 | 1 | Jens Roos / Fabian Bein | vs | Jens Teske / Nikolai Lutum | 1:0 |
| 3 | 7 | Fabián Gaido / Alawi Al-Madari | vs | Gerrit Witt / Florencia Garcia | 0:1 |
| 4 | 6 | Leon Hagemann / Yannic Stoll | vs | Conny Hutter / Maximilian Türk | 1:0 |
| 5 | 5 | Thomas Holzbrecher / Daniel Heins | vs | Kay Dzikonski / Patrick Bettinger | 0:1 |
| 6 | 2 | Jesus Rosa Aparici / Matias Stanojevic Cardenas | vs | Anne Kathrin Stapel / Sarah Riebschläger | 0:1 |
| 7 | 3 | Wieland Hagen / Nail Firat | vs | Simon Frembgen / Joschka Schöpp | 1:0 |
| 8 | 8 | Nils Brinkmann / Frank Sager | vs | Merlin Buck / Oskar Buck | 1:0 |
| 9 | 4 | Moritz Buchta / Hussein Alsadi | vs | Klaus Sebold / Matze Boos | 0:1 |
| 10 | 6 | Simon Reichenbach / Markus Pohlmann | vs | Cord Mählmann / Constantin Ferber | 0:1 |
| 11 | 9 | Leonard Klinkenstein / David Kowalczyk | vs | Martin Kruse / Hannes Sandl | 1:0 |
| 12 | 7 | Paul Götz / Youssou Binia | vs | Martin von Helversen / Alea Probst | 1:0 |
| 13 | 5 | Marc Schott / Martin Kleßen | vs | Martin Lütke / Tara Zoe Spindler | 1:0 |
| 14 | 4 | Ben Thieme / Justus Aust | vs | Trille Schünke-Bettinger / Elisa Wehling | 0:1 |
| 15 | 1 | Benedikt Lamm / Babak Zarreh Djalaly | vs | Achraf Ahmadou / Moritz Aust | 1:0 |
| 16 | 2 | Peter Trenner / Özgün Karabarlas | vs | Benjamin Krause / Matthias Ostertag | 1:0 |
| 17 | 6 | Peer Junge / Rainer Fu | vs | Philip Breuch / Lina Erhard | 1:0 |
| 18 | 3 | Tim Koch / Jens Schulz | vs | Moritz Haass / Marc Rudoll | 1:0 |
| 19 | 9 | Frank Spieß / Klaus Dürfahrt | vs | Eric Falkenhahn / Guntram Trebs | 1:0 |
| 20 | 8 | Thomas Herold / Daniel Sieh | vs | Daniel Wultschner / Joscha Steinbrenner | 1:0 |
| 21 | 5 | Roman Tsevelev / Özcan Isbiliroglu | vs | Mathias Ernst / Frank Stolze | 1:0 |
| 22 | 4 | Oskar Hofmann / Beate Hofmann | vs | Simon Mackowiak / Roy Müller | 1:0 |
